Welcome to the Spin Chemistry website

Radical Pair Reaction Scheme

The purpose of this website is:


to promote the research field of Spin Chemistry;
to facilitate communication within the Spin Chemistry community;
and to provide information about Spin Chemistry.

What is Spin Chemistry?

Broadly defined, Spin Chemistry deals with the effects of electron and nuclear spins in particular, and magnetic interactions in general, on the rates and yields of chemical reactions. It is manifested as spin polarization in EPR and NMR spectra and the magnetic field dependence of chemical processes. Applications include studies of the mechanisms and kinetics of free radical and biradical reactions in solution, the energetics of photosynthetic electron transfer reactions, and various magnetokinetic effects, including possible biological effects of extremely low frequency and radiofrequency electromagnetic fields, the mechanisms by which animals can sense the Earth’s magnetic field for orientation and navigation, and the possibility of manipulating radical lifetimes so as to control the outcome of their reactions.
Some Spin Chemistry reviews:

Time-resolved electron paramagnetic resonance spectroscopy: history, technique, and application to supramolecular and macromolecular chemistry, M. D. E. Forbes, L. E. Jarocha, S. Y. Sim and V. F. Tarasov, Adv. Phys. Org. Chem., Vol. 47, Ch. 1, pp. 1-83, Elsevier, 2013. Reprint request

Magnetic field effects in chemical kinetics and related phenomena, U. E. Steiner and T. Ulrich, Chem. Rev. 89 (1989) 51-147. Reprint download  Reprint request

Radical pairs in solution, J. R. Woodward, Prog. React. Kinet. Mech. 27 (2002) 165-207. Reprint request

Effects of high magnetic fields on photochemical reactions, Y. Tanimoto and Y. Fujiwara, in Handbook of Photochemistry and Photobiology, Vol. 1: Inorganic Photochemistry, H. S. Nalwa (Ed.), American Scientific Publishers, California, 2003, p. 413. Reprint request

A study of spin chemistry in weak magnetic fields, C. R. Timmel and K. B. Henbest, Phil. Trans. Roy. Soc. London, A 362 (2004) 2573-2589. Reprint request

Quantum beats in radical pairs, V.A. Bagryansky, V.I. Borovkov and Yu. N. Molin, Russ. Chem. Rev. 76 (2007) 493-506. Reprint request 

Magnetic field effects in chemical systems, C. T. Rodgers, Pure Appl. Chem. 81 (2009) 19-43. Reprint download

Chemical magnetoreception in birds: the radical pair mechanism, C. T. Rodgers and P. J. Hore, Proc. Natl. Acad. Sci. USA, 106 (2009) 353-360. Reprint request

Time-resolved studies of radical pairs, J. R. Woodward, T. J. Foster, A. R. Jones, A. T. Salaoru and N. S. Scrutton, Biochem. Soc. Trans. 37 (2009) 358–362. Reprint request

 


Announcements

The 14th Spin Chemistry Meeting (SCM 2015) will take place in Kolkata, India in February or March 2015.

 

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